Executive Summary : | OLEDs are crucial in our daily lives, and recent research has focused on using boron-based molecules as efficient TADF emitters in photoelectric devices. By replacing carbon atoms in polyaromatic hydrocarbons with an isoelectronic BN unit, electron-rich nitrogen and electron-deficient boron centers are introduced, preserving their aromaticity and structural characteristics. Cyclic amino boranes exhibit good thermal and chemical stability, making them suitable for practical device applications. Their energy levels can be tailored through molecular design and modification, allowing for precise control over emission characteristics. A strong understanding of the relationship between TADF property and the solid-state arrangement of aminoboranes is needed for molecular design and crystal engineering. This project aims to develop cyclic aminoboranes systems, design, and evaluate novel luminophores for optoelectronic materials development. |