Research

Chemical Sciences

Title :

Optically Active P,N-ligands and their Applications in Metal Catalysis

Area of research :

Chemical Sciences

Focus area :

Organometallic Chemistry, Catalysis

Principal Investigator :

Dr. Nitin T. Patil, Indian Institute of Science Education and Research (IISER) Bhopal, Madhya Pradesh

Timeline Start Year :

2023

Timeline End Year :

2025

Contact info :

Details

Executive Summary :

Researchers recently reported a new class of chiral hemilabile (P,N)-ligands which are named as Ad-ChetPhos, tBu-ChetPhos, Ad-(H8)ChetPhos and tBu-(H8)ChetPhos. The patent entitled “Optically Active P,N-ligands and their Applications in Metal Catalysis” (Application Number: 202221009636; Filing Date: 23-02-2022; Contributors: Chetan C. Chintawar, Vivek W. Bhoyare and Nitin T. Patil) has already been filed. After filing the patent, the work has been published in J. Am. Chem. Soc., 2022, 144, 7089. In this work, PIs have shown that these ligands can be efficiently used for gold-catalyzed enantioselective 1,2-oxyarylation and 1,2-aminoarylation of alkenes.

Total Budget (INR):

30,20,000

Organizations involved